How to Add New Account or Switch accounts in Google chrome

Add New Account:

 
On your computer, open Chrome.

1. At the top right, click Profile .
2. Click Add.
   
3. Sign In
   If you choose to Sync to your Google Account, your profile name will automatically be your Account name.
4. Choose a name, photo and color scheme.
   

If you choose to turn sync on in Chrome with a Google Account for the new profile, your bookmarks, history, passwords and other settings will sync automatically.

Switch Account: 
 

1. On your computer, open Chrome.
2. At the top right, click Profile .

Choose the profile you want to switch to.

Remove a profile:

Please refer to How to remove a Chrome profile from a Chromebook or Chrome browser